Connect wavecom to your pc's RS-232 and talk with it using qextserial just like you did to talk with your microcontroller.
The difference is that you must use the AT commands. I'm sure they are ale listed in some manual you got with the modem.
As katrina wrote, try to send sms manualy first, using hyperterminal or some other serial terminal software. Usually those modems are default at 115200, 8bit and no parity.
After power-on just send to RS something like that
AT //your command
OK //modem response
ATE0 //this is very usefull - turning off local echo
OK //modem response
AT+CPIN="1234" //enter pin number
OK //modem response
AT+CREG=1
OK
AT //your command
OK //modem response
ATE0 //this is very usefull - turning off local echo
OK //modem response
AT+CPIN="1234" //enter pin number
OK //modem response
AT+CREG=1
OK
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In your software you should end commands you send by "\r\n". Most modems will send anything to you starting and finishing the message using "\r\n". So in fact you'll receive "\r\nOK\r\n".
So again, try do what you need manually, then write Qt software doing this for you. It's not really difficult
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